Short answer: 22.4 L at 273.15 K heated to 546.3 K at constant pressure becomes44.8 L — the volume doubles because the absolute temperature doubled. Doubling 273.15 in Celsius instead would give an answer that is simply wrong.
The three ratios in one equation
Hold temperature fixed and it is Boyle’s law; hold pressure fixed and it is Charles’s law; hold volume fixed and it is Gay-Lussac’s law. The page prints both sides of the equation after solving, so the equality can be checked rather than assumed.
Worked example
A tyre at 2.2 bar and 300 K is driven until it reaches 320 K at the same volume: P₂ = 2.2 × 320 ÷ 300 = 2.347 bar, a rise of about 7%. That is the real reason a hot tyre reads high, and it is also why 2.2 is specified cold.